使用Application.Run(new MyForm2());，然后单击按钮以WPF Window在主窗体上为中心创建一个。

public class MyForm2 : Form {

    public MyForm2() {
        this.Size = new Size(600,600);
        this.StartPosition = FormStartPosition.CenterScreen;
        Button btn = new Button { Text = "New Window", AutoSize = true, AutoSizeMode = AutoSizeMode.GrowAndShrink };
        btn.Click += btn_Click;
        Controls.Add(btn);
    }

    void btn_Click(object sender, EventArgs e) {
        var w = new System.Windows.Window();
        w.SourceInitialized += w_SourceInitialized;
        w.Width = 400.0; // number of actual pixels might be different
        w.Height = 400.0; // depending on DPI. My laptop is 120 dpi, so 400.0 -> 400 * 120 / 96 = 500 pixels.
        w.Title = "WPF Window";
        w.ShowDialog();
    }

    void w_SourceInitialized(object sender, EventArgs e) {
        var w = (System.Windows.Window) sender;
        WindowInteropHelper helper = new WindowInteropHelper(w);
        //w.WindowStartupLocation = System.Windows.WindowStartupLocation.CenterOwner; does nothing
        int GWL_HWNDPARENT = -8;
        SetWindowLongInternal(helper.Handle, GWL_HWNDPARENT, this.Handle);

        Rectangle r = this.Bounds;
        RECT r2 = new RECT();
        GetWindowRect(helper.Handle, out r2);
        int w2 = r2.Right - r2.Left;
        int h2 = r2.Bottom - r2.Top;

        int x2 = r.X + (r.Width - w2) / 2;
        int y2 = r.Y + (r.Height - h2) / 2;

        uint SWP_NOSIZE        = 0x0001;
        uint SWP_NOZORDER      = 0x0004;
        uint SWP_NOREDRAW      = 0x0008;
        uint SWP_NOACTIVATE    = 0x0010;
        uint SWP_NOCOPYBITS    = 0x0100;
        uint SWP_NOOWNERZORDER = 0x0200;
        uint flags = SWP_NOACTIVATE | SWP_NOCOPYBITS | SWP_NOOWNERZORDER | SWP_NOREDRAW | SWP_NOSIZE | SWP_NOZORDER;

        SetWindowPos(helper.Handle, IntPtr.Zero, x2, y2, 0, 0, flags);
    }

    [StructLayout(LayoutKind.Sequential)]
    private struct RECT {
        public int Left;
        public int Top;
        public int Right;
        public int Bottom;
    }

    [DllImport("user32.dll")]
    private static extern bool GetWindowRect(IntPtr hWnd, out RECT lpRect);

    [DllImport("user32.dll", SetLastError=true)]
    [return: MarshalAs(UnmanagedType.Bool)]
    private static extern bool SetWindowPos(IntPtr hWnd, IntPtr hWndInsertAfter, int x, int y, int w, int h, uint uFlags);

    [DllImport("user32.dll", SetLastError=true)]
    private static extern int SetWindowLong(IntPtr hWnd, int nIndex, IntPtr dwNewLong);
    [DllImport("user32.dll", SetLastError=true)]
    private static extern int SetWindowLongPtr(IntPtr hWnd, int nIndex, IntPtr dwNewLong);

    private static int SetWindowLongInternal(IntPtr hWnd, int nIndex, IntPtr dwNewLong) {
        if (IntPtr.Size == 4)
            return SetWindowLong(hWnd, nIndex, dwNewLong);

        return SetWindowLongPtr(hWnd, nIndex, dwNewLong);
    }
}